SAP is typically used as the raw materials of sanitary napkins. It helps improve capacity for better retention in a sanitary napkins, allowing the sanitary napkin to be thinner with improved performance and less usage of pine fluff pulp.
The molecular structure of the polyacrylate has sodium carboxylate groups hanging off the main chain. When it comes in contact with water, the sodium detaches itself, leaving only carboxyl ions.Being negatively charged, these ions repel one another so that the polymer unwinds and absorbs water, which is attracted by the sodium atoms. The polymer also has cross-links, which effectively leads to a three-dimensional structure. It has high molecular weight of more than a million; thus, instead of getting dissolved, it solidifies into a gel. The Hydrogen in the water (H-O-H) is trapped by the acrylate due to the atomic bonds associated with the polarity forces between the atoms. Electrolytes in the liquid, such as salt minerals (urine contains 0.9% of minerals), reduce polarity, thereby affecting superabsorbent properties, especially with regard to the superabsorbent capacity for liquid retention.
This is the main reason why pad containing SAP should never be tested with plain water. Linear molecular configurations have less total capacity than non-linear molecules but, on the other hand, retention of liquid in a linear molecule is higher than in a non-linear molecule, due to improved polarity.
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